Method for Development of Probabilistic Emission Inventories: Example Case Study for Utility NOx Emissions

Advances in methodology and computing power enable the application of a quantitative approach to characterizing both variability and uncertainty in emission factors. Variability refers to actual differences in emissions from one source to another due to differences in feedstock composition, design, maintenance, and operation. Uncertainty refers to lack of knowledge regarding the true emissions because of measurement errors (both random and systematic), limited sample sizes (statistical random sampling error), and non-representativeness (which can introduce additional errors, including systematic errors). The set of numerical methods generically known as bootstrap simulation are a powerful tool for characterization of both variability and random sampling error. In this paper, we demonstrate the use of bootstrap simulation and related techniques for the quantification of variability and uncertainty for a selected example of NOx emissions from coal-fired power plants. We have developed a prototype software tool that enables a user to display data sets for emission factors and activity factors for selected power plant technology groups. The user can select a parametric distribution to fit to the data. The user enters information regarding the number of power plant units in the inventory, and can display a variety of results regarding both variability and uncertainty in the inputs to the inventory, as well as uncertainty in various outputs of the inventory. While our example is focused upon emission factors for a selected criteria pollutant, the same methodology can be applied to other pollutants (e.g., hazardous air pollutants, greenhouse gases). The policy relevance of probabilistic inventories will be discussed.